Document Detail


A Practical Synthetic Route to Enantiopure 6-Substituted cis-Decahydroquinolines.
MedLine Citation:
PMID:  22133083     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Starting from 4-substituted cyclohexanones, a practical synthetic route to enantiopure 6-substituted cis-decahydroquinolines has been developed, the key steps being a stereoselective cyclocondensation of an unsaturated δ-keto ester derivative with (R)-phenylglycinol and the stereoselective hydrogenation of the resulting tricyclic oxazoloquinolone lactams.
Authors:
Mercedes Amat; Laura Navío; Núria Llor; Elies Molins; Joan Bosch
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-12-1
Journal Detail:
Title:  Organic letters     Volume:  -     ISSN:  1523-7052     ISO Abbreviation:  -     Publication Date:  2011 Dec 
Date Detail:
Created Date:  2011-12-2     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Laboratory of Organic Chemistry, Faculty of Pharmacy, and Institute of Biomedicine (IBUB), University of Barcelona, 08028-Barcelona, Spain, and Institut de Ciència de Materials de Barcelona (CSIC), Campus UAB, 08193-Cerdanyola, Spain.
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