Document Detail


Practical radical cyclizations with arylboronic acids and trifluoroborates.
MedLine Citation:
PMID:  21923108     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Practical radical cyclizations using organoboronic acids and trifluoroborates take place in water, open to air, and in a scalable fashion employing catalytic silver nitrate and stoichiometric potassium persulfate. Both Pschorr-type cyclizations and tandem radical cyclization/trap cascades are described, illustrating the utility of these mild conditions for the generation of polycyclic scaffolds.
Authors:
Jonathan W Lockner; Darryl D Dixon; Rune Risgaard; Phil S Baran
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Publication Detail:
Type:  Journal Article; Research Support, N.I.H., Extramural; Research Support, Non-U.S. Gov't     Date:  2011-09-16
Journal Detail:
Title:  Organic letters     Volume:  13     ISSN:  1523-7052     ISO Abbreviation:  Org. Lett.     Publication Date:  2011 Oct 
Date Detail:
Created Date:  2011-10-14     Completed Date:  2011-12-21     Revised Date:  2013-12-13    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  United States    
Other Details:
Languages:  eng     Pagination:  5628-31     Citation Subset:  IM    
Copyright Information:
© 2011 American Chemical Society
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MeSH Terms
Descriptor/Qualifier:
Borates / chemistry*
Boronic Acids / chemistry*
Catalysis
Cyclization
Hydrocarbons, Fluorinated / chemistry*
Molecular Structure
Polycyclic Hydrocarbons, Aromatic / chemical synthesis*,  chemistry
Water / chemistry
Grant Support
ID/Acronym/Agency:
GM-073949/GM/NIGMS NIH HHS; R01 CA134785/CA/NCI NIH HHS; R01 CA134785-02/CA/NCI NIH HHS; R01 GM073949/GM/NIGMS NIH HHS; R01 GM073949-08/GM/NIGMS NIH HHS
Chemical
Reg. No./Substance:
0/Borates; 0/Boronic Acids; 0/Hydrocarbons, Fluorinated; 0/Polycyclic Hydrocarbons, Aromatic; 059QF0KO0R/Water
Comments/Corrections

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