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A Powerful Aluminium Catalyst for the Synthesis of Highly Functional Organic Carbonates.
MedLine Citation:
PMID:  23302007     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
An aluminium complex based on an amino triphenolate ligand scaffold shows unprecedented high activity (initial TOFs up to 36,000 h-1), substrate scope and functional group tolerance in the formation of highly functional organic carbonates prepared from epoxides and CO2. The developed catalytic protocol is further characterized by low catalyst loadings and relative mild reaction conditions using a cheap, abundant and non-toxic metal.
Authors:
Christopher J Whiteoak; Nicola Kielland; Victor Laserna; Eduardo C Escudero Adán; Eddy Martin; Arjan Willem Kleij
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-10
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  -     ISSN:  1520-5126     ISO Abbreviation:  J. Am. Chem. Soc.     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-10     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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