Document Detail


Polyporous Metal-Coordination Frameworks.
MedLine Citation:
PMID:  22375911     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Starting from a chiral building block-α-cyclodextrin-and rubidium salts, the crystallization of a complex of chiral helices, which constitute a "green" porous coordination polymer, has been realized. Cyclodextrin molecules coordinated by rubidium ions form porous, infinitely long left-handed helical channels, interdigitated with each other. A theoretical examination of the potential of this new material to act as a medium for chiral separation is presented.
Authors:
Jeremiah J Gassensmith; Ronald A Smaldone; Ross S Forgan; Christopher E Wilmer; David B Cordes; Youssry Y Botros; Alexandra M Z Slawin; Randall Q Snurr; J Fraser Stoddart
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-2-29
Journal Detail:
Title:  Organic letters     Volume:  -     ISSN:  1523-7052     ISO Abbreviation:  -     Publication Date:  2012 Feb 
Date Detail:
Created Date:  2012-3-1     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Center for the Chemistry of Integrated Systems, Department of Chemistry, Department of Materials Science, Department of Chemical & Biological Engineering, Northwestern University , 2145 Sheridan Road, Evanston, Illinois 60208, United States, NanoCentury KAIST Institute and Graduate School of EEWS (WCU), Korea Advanced Institute of Science and Technology (KAIST), 373-1 Guseong Dong, Yuseong Gu, Daejeon 305-701, Republic of Korea, University of St. Andrews , Eastchem School of Chemistry, St. Andrews, Fife KY16 9ST, U.K., Intel Labs , Building RNB-6-61, 2200 Mission College Boulevard, Santa Clara, California 95054, United States, and National Center for Nano Technology Research, King Abdulaziz City for Science and Technology (KACST), P.O. Box 6086, Riyadh 11442, Kingdom of Saudi Arabia.
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