Document Detail


Polyoxometalate-supported ruthenium nanoparticles as bifunctional heterogeneous catalysts for the conversions of cellobiose and cellulose into sorbitol under mild conditions.
MedLine Citation:
PMID:  21789299     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Ru nanoparticles loaded on a Keggin-type polyoxometalate (Cs(3)PW(12)O(40)), which did not possess strong intrinsic acidity, efficiently catalysed the conversions of cellobiose and cellulose into sorbitol in water medium in H(2) at ≤433 K. The Brønsted acid sites generated in situ from H(2) have been demonstrated to play a key role in the formation of sorbitol.
Authors:
Mi Liu; Weiping Deng; Qinghong Zhang; Yanliang Wang; Ye Wang
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-7-25
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  -     Publication Date:  2011 Jul 
Date Detail:
Created Date:  2011-7-26     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China. zhangqh@xmu.edu.cn wangye@xmu.edu.cn.
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