| Polymers and surfactants on the basis of renewable resources. | |
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MedLine Citation:
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PMID: 11235676 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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A new strategy for the preparation of different polymers and special surfactants was developed. First, unsaturated fatty acid methyl esters obtained from plant oils were converted to terminally unsaturated esters and alpha-olefins by metathesis with ethylene using heterogeneous rhenium or homogeneous ruthenium catalysts. These esters were directly copolymerized with ethylene by an insertion-type palladium-catalyzed polymerization to functionalized polyolefins. Polyesters were synthesized by metathetical dimerization of omega-unsaturated esters and subsequent polycondensation of the produced internally unsaturated dicarboxylic esters or by acidic transesterification with petrochemical diols and additional acyclic diene metathesis polymerization. Omega-epoxy fatty acid methyl esters, achieved by a new method of chemo-enzymatic epoxidation, were converted into polyethers with comb-structure catalyzed by aluminoxanes on the one hand and into sugar surfactants by nucleophilic ring-opening with amino carbohydrates on the other hand. |
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Authors:
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S Warwel; F Brüse; C Demes; M Kunz; M Rüsch gen Klaas |
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Publication Detail:
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Type: Journal Article; Research Support, Non-U.S. Gov't |
Journal Detail:
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Title: Chemosphere Volume: 43 ISSN: 0045-6535 ISO Abbreviation: Chemosphere Publication Date: 2001 Apr |
Date Detail:
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Created Date: 2001-03-06 Completed Date: 2001-05-17 Revised Date: 2006-11-15 |
Medline Journal Info:
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Nlm Unique ID: 0320657 Medline TA: Chemosphere Country: England |
Other Details:
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Languages: eng Pagination: 39-48 Citation Subset: IM |
Affiliation:
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Federal Centre for Cereal, Potato and Lipid Research, Institute for Biochemistry and Technology of Lipids, HP Kaufmann-Institute, Münster, Germany. ibtfett@uni-muenster.de |
Export Citation:
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APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
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Carbohydrate Metabolism Conservation of Natural Resources* Fatty Acids / metabolism Plant Oils Polyesters Polymers / chemical synthesis* Surface-Active Agents / chemical synthesis* |
| Chemical | |
Reg. No./Substance:
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0/Fatty Acids; 0/Plant Oils; 0/Polyesters; 0/Polymers; 0/Surface-Active Agents |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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