| Platinum complexes of cationic ligands for the aerobic oxidation of "inert" perfluoro-substituted alcohols. | |
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MedLine Citation:
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PMID: 23340598 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Trifluoroethanol was oxidized with O(2) to trifluoroethyl trifluoracetate (>98% selectivity) using Pt(II)(dppz)Cl(2) as a catalyst in the presence of H(2)SO(4); Pt(II)(phen)Cl(2) was inactive. Kinetic isotope effects suggest the C-H bond activation as the rate determining step and DFT calculations showed different frontier orbitals for Pt(II)(dppz) and Pt(II)(phen)-based catalysts. |
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Authors:
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Haviv Ben-David; Mark A Iron; Ronny Neumann |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2013-1-23 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1364-548X ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2013 Jan |
Date Detail:
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Created Date: 2013-1-23 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, Israel. Ronny.Neumann@weizmann.ac.il. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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