Document Detail


Platinum complexes of cationic ligands for the aerobic oxidation of "inert" perfluoro-substituted alcohols.
MedLine Citation:
PMID:  23340598     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Trifluoroethanol was oxidized with O(2) to trifluoroethyl trifluoracetate (>98% selectivity) using Pt(II)(dppz)Cl(2) as a catalyst in the presence of H(2)SO(4); Pt(II)(phen)Cl(2) was inactive. Kinetic isotope effects suggest the C-H bond activation as the rate determining step and DFT calculations showed different frontier orbitals for Pt(II)(dppz) and Pt(II)(phen)-based catalysts.
Authors:
Haviv Ben-David; Mark A Iron; Ronny Neumann
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-23
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-23     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, Israel. Ronny.Neumann@weizmann.ac.il.
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