Document Detail


Photoswitching of the second-order nonlinearity of a tetrahedral octupolar multi DTE-based copper(i) complex.
MedLine Citation:
PMID:  22986301     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The modulation of the quadratic NLO response of an octupolar metal-based chromophore featuring four photochromic dithienylethene units is reported. Quantum mechanical simulations are consistent with a full switching of the DTE units and reproduce the strong enhancement of the NLO response.
Authors:
Hiroyuki Nitadori; Lucie Ordronneau; Julien Boixel; Denis Jacquemin; Abdou Boucekkine; Anu Singh; Munetaka Akita; Isabelle Ledoux; Véronique Guerchais; Hubert Le Bozec
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-9-17
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Sep 
Date Detail:
Created Date:  2012-9-18     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
UMR 6226 CNRS-Université de Rennes 1, Institut des Sciences Chimiques de Rennes, Campus de Beaulieu, 35042 Rennes, France. lebozec@univ-rennes1.fr.
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