Document Detail


Photoinduced, Multi-Step, Charge Separation in a Heteroleptic Cu(I) bis-Phenanthroline Based Donor-Chromophore-Acceptor Triad.
MedLine Citation:
PMID:  23030254     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
A molecular triad assembly consisting of an electron donor, a bisphenanthrolinecopper(I) chromophore and an electron acceptor has been prepared. Under visible light excitation, this assembly undergoes efficient (ca. 50%), multi-step, photoinduced, charge-separated state formation. The di-radical-cation charge separated state has a lifetime of >100 ns and stores >1.0 V of energy. This system constitutes a earth-abundant functional analog of related Ru(bpy)3 triad systems.
Authors:
Megan S Lazorski; Riley H Gest; C Michael Elliott
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-3
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  -     ISSN:  1520-5126     ISO Abbreviation:  J. Am. Chem. Soc.     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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