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Photoelectron Spectroscopy of Anilinide and Acidity of Aniline.
MedLine Citation:
PMID:  22420311     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The photoelectron spectrum of the anilinide ion has been measured. The spectrum exhibits a vibrational progression of the CCC in-plane bending mode of the anilino radical in its electronic ground state. The observed fundamental frequency is 524 ± 10 cm(-1). The electron affinity (EA) of the radical is determined to be 1.607 ± 0.004 eV. The EA value is combined with the N-H bond dissociation energy of aniline in a negative ion thermochemical cycle to derive the deprotonation enthalpy of aniline at 0 K; Δ(acid)H(0)(PhHN-H) = 1535.4 ± 0.7 kJ mol(-1). Temperature corrections are made to obtain the corresponding value at 298 K and the gas-phase acidity; Δ(acid)H(298)(PhHN-H) = 1540.8 ± 1.0 kJ mol(-1) and Δ(acid)G(298)(PhHN-H) = 1509.2 ± 1.5 kJ mol(-1), respectively. The compatibility of this value in the acidity scale that is currently available is examined by utilizing the acidity of acetaldehyde as a reference.
Authors:
Scott W Wren; Kristen M Vogelhuber; Takatoshi Ichino; John F Stanton; W Carl Lineberger
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-3-15
Journal Detail:
Title:  The journal of physical chemistry. A     Volume:  -     ISSN:  1520-5215     ISO Abbreviation:  -     Publication Date:  2012 Mar 
Date Detail:
Created Date:  2012-3-16     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9890903     Medline TA:  J Phys Chem A     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
JILA, University of Colorado and National Institute of Standards and Technology , Department of Chemistry and Biochemistry, University of Colorado , Boulder, Colorado 80309-0440, United States.
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