| Photocatalytic reversible amination of α-keto acids on a ZnS surface: implications for the prebiotic metabolism. | |
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MedLine Citation:
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PMID: 22237955 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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We report the enzyme-like reversible amination of four intermediates pertinent to the reductive tricarboxylic acid cycle on a photo-irradiated surface of mineral sphalerite (ZnS). Given its prevalence in the waters of early Earth, we suggest that the mineral-based photochemistry might have catalyzed the homeostasis of prebiotic metabolic systems. |
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Authors:
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Wei Wang; Qiliang Li; Bin Yang; Xiaoyang Liu; Yanqiang Yang; Wenhui Su |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-1-12 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1364-548X ISO Abbreviation: - Publication Date: 2012 Jan |
Date Detail:
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Created Date: 2012-1-12 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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CCMST, Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology, Harbin 150080, China. wwang_ol@hit.edu.cn. |
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