| Photoactivation of metal-halogen bonds in a Ni(ii) NHC complex. | |
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MedLine Citation:
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PMID: 23280412 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Photolysis of [Ni(II)(μ-Cl)Cl(IPr)](2) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) activates the Ni-Cl bonds to furnish [Ni(I)(μ-Cl)(IPr)](2). Consistent with this photochemistry, a TD-DFT calculation for square planar Ni(ii) centre reveals that light excitation leads to the population of orbitals with σ*(Ni-Cl) character. |
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Authors:
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Chang Hoon Lee; Daniel A Lutterman; Daniel G Nocera |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2013-1-2 |
Journal Detail:
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Title: Dalton transactions (Cambridge, England : 2003) Volume: - ISSN: 1477-9234 ISO Abbreviation: Dalton Trans Publication Date: 2013 Jan |
Date Detail:
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Created Date: 2013-1-2 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 101176026 Medline TA: Dalton Trans Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Department of Chemistry, Massachusetts Institute of Technology, 6-355, 77 Mass Ave., Cambridge, MA 02139-4307, USA. nocera@mit.edu. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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