Document Detail


A Photo Lewis Acid Generator, or "PhLAG": Controlled Photo Re-lease of B(C6F5)3.
MedLine Citation:
PMID:  22651906     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
A molecule that releases the strong organometallic Lewis acid B(C6F5)3 upon irradiation with 254 nm light has been developed. This photo Lewis acid generator, or "PhLAG" now enables the photocontrolled initiation of several reactions catalyzed by this important Lewis acid. Herein is described the synthesis of the triphenylsulfonium salt of a carbamato borate based on a carbazole function, its establishment as a PhLAG, and the application of the photo release of B(C6F5)3 to the fabrication of thin films of a pol-ysiloxane material.
Authors:
Andrey Y Khalimon; Warren Edward Piers; James M Blackwell; David Jason Michalak; Masood Parvez
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-5-31
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  -     ISSN:  1520-5126     ISO Abbreviation:  -     Publication Date:  2012 May 
Date Detail:
Created Date:  2012-6-1     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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