| Phosphorescent chemosensor for Hg(2+) and acetonitrile based on iridium(iii) complex. | |
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MedLine Citation:
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PMID: 23014114 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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A new phosphorescent chemosensor for Hg(2+) and acetonitrile (MeCN) based on iridium(iii) complex Ir(dpp)(2)(dtc) (, dppH = 4,6-diphenylpyrimidine, dtcH = diethyl dithiocarbamic acid) was realized. Upon addition of a tetrahydrofuran (THF) solution of Hg(2+), the dichloromethane (DCM) solution of gave a visual color change and significant fluorescent quenching. When MeCN was added, a new fluorescent emission emerged, which constituted a selective MeCN phosphorescent chemosensor. Complex has been developed as an AND logic gate with Hg(2+) and MeCN as inputs. |
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Authors:
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Qun-Bo Mei; Yuan-Hui Guo; Bi-Hai Tong; Jie-Na Weng; Bin Zhang; Wei Huang |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-9-27 |
Journal Detail:
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Title: The Analyst Volume: - ISSN: 1364-5528 ISO Abbreviation: Analyst Publication Date: 2012 Sep |
Date Detail:
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Created Date: 2012-9-27 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0372652 Medline TA: Analyst Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Key Laboratory for Organic Electronics & Information Displays (KLOEID), Institute of Advanced Materials (IAM), Nanjing University of Posts and Telecommunications (NUPT), Nanjing, 210046, P. R. China. iamqbmei@njupt.edu.cn iamwhuang@njupt.edu.cn. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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