Document Detail


Perpendicularly oriented lamellae in poly(3-hydroxybutyric acid-co-3-hydroxyvaleric acid) blended with an amorphous polymer: ultra-thin to thick films.
MedLine Citation:
PMID:  23318504     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The oppositely oriented lamellae in ridge and valley bands of ring-banded spherulites in biodegradable poly(3-hydroxybutyric acid-co-3-hydroxyvaleric acid) (PHBV) interacting with amorphous poly(vinyl acetate) (PVAc) were examined using polarized-light optical, scanning electron, and atomic-force microscopy techniques (POM, SEM, AFM). Solvent-etching and fracturing were utilized for probing the interior morphology of the large-size ring-banded spherulites in PHBV/PVAc (70/30) blend [T(c) = 110 °C] films or thick bulk of various thicknesses. SEM analysis revealed that dual ridges of two opposite-oriented lamellae correspond to two-color bands (yellow and blue) of successive rings in POM micrographs. Fracture of thick blend samples further exposed that interior 3D spherulites were composed of sheath-kebab (similar to corrugated board) lamellae of two mutually perpendicular orientations.
Authors:
Chean-Cheng Su; Eamor M Woo; Ya-Ting Hsieh
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-15
Journal Detail:
Title:  Physical chemistry chemical physics : PCCP     Volume:  -     ISSN:  1463-9084     ISO Abbreviation:  Phys Chem Chem Phys     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-15     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100888160     Medline TA:  Phys Chem Chem Phys     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemical and Materials Engineering, National University of Kaohsiung, No. 700, Kaohsiung University Rd., Nan-Tzu Dist., Kaohsiung, 811, Taiwan. ccsu@nuk.edu.tw.
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