Document Detail

Perfluorinated aromatic spacers for sensitizing europium(III) centers in dinuclear oligomers: better than the best by chemical design?
MedLine Citation:
PMID:  23047755     Owner:  NLM     Status:  MEDLINE    
Transfer news: the use of a simple method allows the various sensitization steps in Eu(III) -containing complexes to be deciphered. Incorporation of an increasing number of electron-withdrawing fluorine atoms on the rigid and electronically tunable phenyl spacer between two tridentate binding units (see picture, red O, dark blue N) affects the quantum yield, intersystem crossing, and energy-transfer processes in a rational way.
Jean-François Lemonnier; Lucille Babel; Laure Guénée; Prasun Mukherjee; David H Waldeck; Svetlana V Eliseeva; Stéphane Petoud; Claude Piguet
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Publication Detail:
Type:  Journal Article; Research Support, N.I.H., Extramural; Research Support, Non-U.S. Gov't     Date:  2012-10-09
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  51     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-10-31     Completed Date:  2013-06-18     Revised Date:  2013-11-07    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  Germany    
Other Details:
Languages:  eng     Pagination:  11302-5     Citation Subset:  IM    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Department of Inorganic Analytical Chemistry, University of Geneva, Switzerland.
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MeSH Terms
Coordination Complexes / chemistry*
Europium / chemistry*
Hydrocarbons, Fluorinated / chemistry
Luminescent Measurements
Molecular Structure
Quantum Theory
X-Ray Diffraction
Grant Support
Reg. No./Substance:
0/Coordination Complexes; 0/Hydrocarbons, Fluorinated; 0/Ligands; 7440-53-1/Europium

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