Document Detail


Perfluorinated aromatic spacers for sensitizing europium(III) centers in dinuclear oligomers: better than the best by chemical design?
MedLine Citation:
PMID:  23047755     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Transfer news: the use of a simple method allows the various sensitization steps in Eu(III) -containing complexes to be deciphered. Incorporation of an increasing number of electron-withdrawing fluorine atoms on the rigid and electronically tunable phenyl spacer between two tridentate binding units (see picture, red O, dark blue N) affects the quantum yield, intersystem crossing, and energy-transfer processes in a rational way.
Authors:
Jean-François Lemonnier; Lucille Babel; Laure Guénée; Prasun Mukherjee; David H Waldeck; Svetlana V Eliseeva; Stéphane Petoud; Claude Piguet
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Publication Detail:
Type:  Journal Article; Research Support, N.I.H., Extramural; Research Support, Non-U.S. Gov't     Date:  2012-10-09
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  51     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-10-31     Completed Date:  2013-06-18     Revised Date:  2013-11-07    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  Germany    
Other Details:
Languages:  eng     Pagination:  11302-5     Citation Subset:  IM    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Department of Inorganic Analytical Chemistry, University of Geneva, Switzerland.
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MeSH Terms
Descriptor/Qualifier:
Coordination Complexes / chemistry*
Europium / chemistry*
Hydrocarbons, Fluorinated / chemistry
Ligands
Luminescent Measurements
Molecular Structure
Quantum Theory
Thermodynamics
X-Ray Diffraction
Grant Support
ID/Acronym/Agency:
R21 EB008257/EB/NIBIB NIH HHS; R21-EB008257-01A1/EB/NIBIB NIH HHS
Chemical
Reg. No./Substance:
0/Coordination Complexes; 0/Hydrocarbons, Fluorinated; 0/Ligands; 7440-53-1/Europium
Comments/Corrections

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