| Perfluorinated Aromatic Spacers for Sensitizing Europium(III) Centers in Dinuclear Oligomers: Better than the Best by Chemical Design? | |
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MedLine Citation:
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PMID: 23047755 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Transfer news: The use of a simple method allows the various sensitization steps in Eu(III) -containing complexes to be deciphered. Incorporation of an increasing number of electron-withdrawing fluorine atoms on the rigid and electronically tunable phenyl spacer between two tridentate binding units (see picture, red O, dark blue N) affects the quantum yield, intersystem crossing, and energy transfer processes in a rational way. |
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Authors:
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Jean-François Lemonnier; Lucille Babel; Laure Guénée; Prasun Mukherjee; David H Waldeck; Svetlana V Eliseeva; Stéphane Petoud; Claude Piguet |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-10-9 |
Journal Detail:
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Title: Angewandte Chemie (International ed. in English) Volume: - ISSN: 1521-3773 ISO Abbreviation: Angew. Chem. Int. Ed. Engl. Publication Date: 2012 Oct |
Date Detail:
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Created Date: 2012-10-10 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0370543 Medline TA: Angew Chem Int Ed Engl Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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Department of Inorganic Analytical Chemistry, University of Geneva, 30 quai E. Ansermet, CH-1211 Geneva 4 (Switzerland). |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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