| Pentavalent uranium trans-dihalides and -pseudohalides. | |
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MedLine Citation:
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PMID: 22497012 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Pentavalent uranium complexes of the formula U(V)X(2)[N(SiMe(3))(2)](3) (X = F(-), Cl(-), Br(-), N(3)(-), NCS(-)) are accessible from the oxidation of U(III)[N(SiMe(3))(2)](3) through two sequential, one-electron oxidation reactions (halides) and substitution through salt metathesis (pseudohalides). Uranium(v) mixed-halides are also synthesized by successive one-electron oxidation reactions. |
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Authors:
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Andrew J Lewis; Eiko Nakamaru-Ogiso; James M Kikkawa; Patrick J Carroll; Eric J Schelter |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-4-11 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1364-548X ISO Abbreviation: - Publication Date: 2012 Apr |
Date Detail:
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Created Date: 2012-4-12 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, Pennsylvania 19104, USA. schelter@sas.upenn.edu. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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