Document Detail

Penifulvins B-E and a silphinene analogue: sesquiterpenoids from a fungicolous isolate of Penicillium griseofulvum.
MedLine Citation:
PMID:  17125229     Owner:  NLM     Status:  MEDLINE    
Penifulvins B-E (2-5), four new sesquiterpenoids with a dioxa[]fenestrane ring system, have been isolated from cultures of an isolate of Penicillium griseofulvum (NRRL 35584), together with a new silphinene derivative, 12-hydroxysilphinene-15-oic acid (6). Penifulvins B-E (2-5) are oxidized analogues of penifulvin A (1) and were identified by analysis of NMR and MS data. 12-Hydroxysilphinen-15-oic acid (6) is biogenetically similar, and penifulvins A-E are presumed to be derived from a silphinene precursor. The structures of 2-6, including absolute configuration, were assigned by analysis of NMR data and application of chemical methods.
Sang Hee Shim; James B Gloer; Donald T Wicklow
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't; Research Support, U.S. Gov't, Non-P.H.S.    
Journal Detail:
Title:  Journal of natural products     Volume:  69     ISSN:  0163-3864     ISO Abbreviation:  J. Nat. Prod.     Publication Date:  2006 Nov 
Date Detail:
Created Date:  2006-11-27     Completed Date:  2007-02-12     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  7906882     Medline TA:  J Nat Prod     Country:  United States    
Other Details:
Languages:  eng     Pagination:  1601-5     Citation Subset:  IM    
Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, USA.
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MeSH Terms
Molecular Structure
Nuclear Magnetic Resonance, Biomolecular
Penicillium / chemistry*
Sesquiterpenes / chemistry*,  isolation & purification*
Reg. No./Substance:

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