Document Detail


Pd(II)-catalyzed enantioselective C-H olefination of diphenylacetic acids.
MedLine Citation:
PMID:  20017549     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Pd(II)-catalyzed enantioselective C-H olefination of diphenylacetic acid substrates has been achieved through the use of monoprotected chiral amino acid ligands. The absolute configuration of the resulting olefinated products is consistent with that of a proposed C-H insertion intermediate.
Authors:
Bing-Feng Shi; Yang-Hui Zhang; Jonathan K Lam; Dong-Hui Wang; Jin-Quan Yu
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Publication Detail:
Type:  Journal Article; Research Support, N.I.H., Extramural; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Journal of the American Chemical Society     Volume:  132     ISSN:  1520-5126     ISO Abbreviation:  J. Am. Chem. Soc.     Publication Date:  2010 Jan 
Date Detail:
Created Date:  2010-01-14     Completed Date:  2010-03-26     Revised Date:  2013-04-12    
Medline Journal Info:
Nlm Unique ID:  7503056     Medline TA:  J Am Chem Soc     Country:  United States    
Other Details:
Languages:  eng     Pagination:  460-1     Citation Subset:  IM    
Affiliation:
Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.
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MeSH Terms
Descriptor/Qualifier:
Aldehydes / chemical synthesis,  chemistry
Alkenes / chemical synthesis*,  chemistry
Catalysis
Crystallography, X-Ray
Cyclization
Diphenylacetic Acids / chemistry*
Lactones / chemical synthesis,  chemistry
Models, Molecular
Molecular Structure
Organometallic Compounds / chemistry*
Palladium / chemistry*
Stereoisomerism
Grant Support
ID/Acronym/Agency:
1 R01 GM084019-01A1/GM/NIGMS NIH HHS; R01 GM084019-02/GM/NIGMS NIH HHS
Chemical
Reg. No./Substance:
0/Aldehydes; 0/Alkenes; 0/Diphenylacetic Acids; 0/Lactones; 0/Organometallic Compounds; 7440-05-3/Palladium
Comments/Corrections

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