| Pd(II)-catalyzed enantioselective C-H olefination of diphenylacetic acids. | |
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MedLine Citation:
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PMID: 20017549 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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Pd(II)-catalyzed enantioselective C-H olefination of diphenylacetic acid substrates has been achieved through the use of monoprotected chiral amino acid ligands. The absolute configuration of the resulting olefinated products is consistent with that of a proposed C-H insertion intermediate. |
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Authors:
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Bing-Feng Shi; Yang-Hui Zhang; Jonathan K Lam; Dong-Hui Wang; Jin-Quan Yu |
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Publication Detail:
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Type: Journal Article; Research Support, N.I.H., Extramural; Research Support, Non-U.S. Gov't |
Journal Detail:
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Title: Journal of the American Chemical Society Volume: 132 ISSN: 1520-5126 ISO Abbreviation: J. Am. Chem. Soc. Publication Date: 2010 Jan |
Date Detail:
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Created Date: 2010-01-14 Completed Date: 2010-03-26 Revised Date: 2013-04-12 |
Medline Journal Info:
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Nlm Unique ID: 7503056 Medline TA: J Am Chem Soc Country: United States |
Other Details:
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Languages: eng Pagination: 460-1 Citation Subset: IM |
Affiliation:
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Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA. |
Export Citation:
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| MeSH Terms | |
Descriptor/Qualifier:
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Aldehydes
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chemical synthesis,
chemistry Alkenes / chemical synthesis*, chemistry Catalysis Crystallography, X-Ray Cyclization Diphenylacetic Acids / chemistry* Lactones / chemical synthesis, chemistry Models, Molecular Molecular Structure Organometallic Compounds / chemistry* Palladium / chemistry* Stereoisomerism |
| Grant Support | |
ID/Acronym/Agency:
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1 R01 GM084019-01A1/GM/NIGMS NIH HHS; R01 GM084019-02/GM/NIGMS NIH HHS |
| Chemical | |
Reg. No./Substance:
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0/Aldehydes; 0/Alkenes; 0/Diphenylacetic Acids; 0/Lactones; 0/Organometallic Compounds; 7440-05-3/Palladium |
| Comments/Corrections | |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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