| Pd-catalyzed double C-H bond activation of diaryl ketones for the synthesis of fluorenones. | |
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MedLine Citation:
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PMID: 22890473 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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An efficient synthesis of fluorenones from diaryl ketones by Pd-catalyzed oxidative cyclization is described. A possible mechanism involving a carbonyl group assisted ortho-C-H activation and cyclometalation followed by a second C-H activation to form a six-membered palladacycle and reductive elimination is proposed. |
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Authors:
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Parthasarathy Gandeepan; Chen-Hsun Hung; Chien-Hong Cheng |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-8-14 |
Journal Detail:
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Title: Chemical communications (Cambridge, England) Volume: - ISSN: 1364-548X ISO Abbreviation: Chem. Commun. (Camb.) Publication Date: 2012 Aug |
Date Detail:
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Created Date: 2012-8-14 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 9610838 Medline TA: Chem Commun (Camb) Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan. chcheng@mx.nthu.edu.tw. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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