Document Detail


Panchromatic Trichromophoric Sensitizer for Dye-Sensitized Solar Cells Using Antenna Effect.
MedLine Citation:
PMID:  21721515     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The first trichromophoric sensitizer, consisting of covalently linked boradiazaindacene (BODIPY), zinc porphyrin (ZnP), and squaraine (SQ) units, has been synthesized by Heck alkynylation to obtain a panchromatic dye, for dye sensitized solar cells (DSSCs). Efficient intramolecular energy transfers (ET) were observed between all chromophoric subunits and enhance the overall conversion efficiency by 25%. The antenna effect is demonstrated by the photoaction spectrum which features all of a chromophore's absorption bands.
Authors:
Julien Warnan; Fabien Buchet; Yann Pellegrin; Errol Blart; Fabrice Odobel
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-7-1
Journal Detail:
Title:  Organic letters     Volume:  -     ISSN:  1523-7052     ISO Abbreviation:  -     Publication Date:  2011 Jul 
Date Detail:
Created Date:  2011-7-4     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Laboratoire CEISAM, Equipe d'ingénierie et de photonique moléculaire UMR CNRS 6230 - Bât. 4 Faculté des Sciences et des Techniques de Nantes BP 92208 2, rue de la Houssinière 44322 Nantes cedex 03, France.
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