Document Detail


Palladium-Catalyzed Desulfitative Conjugate Addition of Aryl Sulfinic Acids and Direct ESI-MS for Mechanistic Studies.
MedLine Citation:
PMID:  22515617     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
A new and efficient method for palladium (II) catalytic desulfitative conjugate addition of arylsulfinic acids with α,β-unsaturated carbonyl compound has been developed. The key reacting intermediates including aryl Pd(II) sulfinic intermediate, aryl Pd(II) and C=O-Pd complexes were captured by ESI-MS/MS, which provide new experimental evidences for the understanding of addition mechanism.
Authors:
Huifeng Wang; Yaming Li; Rong Zhang; Kun Jin; Defeng Zhao; Chunying Duan
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-4-20
Journal Detail:
Title:  The Journal of organic chemistry     Volume:  -     ISSN:  1520-6904     ISO Abbreviation:  -     Publication Date:  2012 Apr 
Date Detail:
Created Date:  2012-4-20     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2985193R     Medline TA:  J Org Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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