| Palladium-Catalyzed Decarboxylative Coupling of Isatoic Anhydrides with Arylboronic Acids. | |
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MedLine Citation:
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PMID: 22013883 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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The decarboxylative coupling of isatoic anhydrides with arylboronic acids was realized for the first time in the presence of Pd(2)(dba)(3) and DPEphos, achieving aryl o-aminobenzoates with yields ranging from moderate to good. The efficiency of this procedure was demonstrated by good compatibility with fluoro, chloro, bromo, nitro, cyano, trifluoromethyl, formacyl, acetyl, thienyl, and naphthyl groups. Preliminary mechanistic experiments using deuterium labeling showed that the oxygen atom was derived from dioxygen. |
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Authors:
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Wei Lu; Jiuxi Chen; Miaochang Liu; Jinchang Ding; Wenxia Gao; Huayue Wu |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2011-10-20 |
Journal Detail:
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Title: Organic letters Volume: - ISSN: 1523-7052 ISO Abbreviation: - Publication Date: 2011 Oct |
Date Detail:
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Created Date: 2011-10-21 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 100890393 Medline TA: Org Lett Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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College of Chemistry & Materials Engineering, Wenzhou University, Wenzhou 325035, P. R. China. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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