Document Detail


Palladium-Catalyzed Decarboxylative Coupling of Isatoic Anhydrides with Arylboronic Acids.
MedLine Citation:
PMID:  22013883     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The decarboxylative coupling of isatoic anhydrides with arylboronic acids was realized for the first time in the presence of Pd(2)(dba)(3) and DPEphos, achieving aryl o-aminobenzoates with yields ranging from moderate to good. The efficiency of this procedure was demonstrated by good compatibility with fluoro, chloro, bromo, nitro, cyano, trifluoromethyl, formacyl, acetyl, thienyl, and naphthyl groups. Preliminary mechanistic experiments using deuterium labeling showed that the oxygen atom was derived from dioxygen.
Authors:
Wei Lu; Jiuxi Chen; Miaochang Liu; Jinchang Ding; Wenxia Gao; Huayue Wu
Related Documents :
16845213 - Kynurenic acid in human saliva--does it influence oral microflora?
10703633 - Strontium nitrate suppresses chemically-induced sensory irritation in humans.
24717543 - Lipid and fatty acids of three edible myctophids, diaphus watasei, diaphus suborbitalis...
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-10-20
Journal Detail:
Title:  Organic letters     Volume:  -     ISSN:  1523-7052     ISO Abbreviation:  -     Publication Date:  2011 Oct 
Date Detail:
Created Date:  2011-10-21     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
College of Chemistry & Materials Engineering, Wenzhou University, Wenzhou 325035, P. R. China.
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  Quantum Dynamics through Conical Intersections: Combining Effective Modes and Quadratic Couplings.
Next Document:  Mitigation of lung injury after accidental exposure to radiation.