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P-C bond formation via P-H addition of a fluoroaryl phosphinic acid to ketones.
MedLine Citation:
PMID:  21072125     Owner:  NLM     Status:  Publisher    
The synthesis, structure and reactivity of the fluoroaryl phosphinic acid HF(4)C(6)-P(O)HOH is reported and compared to a sterically comparable yet non-fluorinated analog with similar size. The fluoroaryl phosphinic acid undergoes reversible P-H addition to the carbonyl functionality of ketones under formation of a P-C bond which is retained in the resulting α-hydroxy phosphinic acid. The latter shows an extended 2D hydrogen bonded network in the solid state.
Andreas Orthaber; Jörg H Albering; Ferdinand Belaj; Rudolf Pietschnig
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Publication Detail:
Journal Detail:
Title:  Journal of fluorine chemistry     Volume:  131     ISSN:  0022-1139     ISO Abbreviation:  -     Publication Date:  2010 Oct 
Date Detail:
Created Date:  2010-11-12     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0373322     Medline TA:  J Fluor Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  1025-1031     Citation Subset:  -    
Department of Chemistry, Inorganic Section, University of Graz, Schubertstr. 1, 8010 Graz, Austria.
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