Document Detail


Oxidation of cycloalkanes by H(2)O(2) using a copper-hemicryptophane complex as a catalyst.
MedLine Citation:
PMID:  23295862     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Efficient alkane C-H bond oxidation was achieved using a newly designed Cu(ii)-hemicryptophane complex. Protection of the copper site in the inner cavity of the host leads to enhanced yields and allows discriminating cyclohexane from cyclooctane or adamantane in competitive experiments.
Authors:
Olivier Perraud; Alexander B Sorokin; Jean-Pierre Dutasta; Alexandre Martinez
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-8
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-8     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Laboratoire de Chimie, CNRS, Université Lyon 1, École Normale Supérieure de Lyon, 46 Allée d'Italie, F-69364 Lyon, France. alexandre.martinez@ens-lyon.fr.
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