Document Detail


Oxidant controlled Pd-catalysed selective oxidation of primary alcohols.
MedLine Citation:
PMID:  23303167     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The oxidant controlled palladium catalysed selective oxidation of primary alcohols to aldehydes or esters was investigated. The electronic properties of the benzylic alcohols and the structure of the oxidant are both important factors in controlling the selectivity between aldehydes and esters. A covalent benzyl ligand derived from BnCl provides η(3) coordination to the Pd centre. This covalent ligand is the key to the selective oxidative esterification of primary alcohols.
Authors:
Chao Liu; Shan Tang; Aiwen Lei
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-10
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-10     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, 430072, P. R. China. aiwenlei@whu.edu.cn.
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