Document Detail


One-pot synthesis and characterization of subnanometre-size benzotriazolate protected copper clusters.
MedLine Citation:
PMID:  22532448     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
A simple one-pot method for the preparation of subnanometre-size benzotriazolate (BTA) protected copper clusters, Cu(n)BTA(m), is reported. The clusters were analyzed by optical and infrared spectroscopy, mass spectrometry and transmission electron microscopy together with computational methods. We suggest a structural motif where the copper core of the Cu(n)BTA(m) clusters is protected by BTA-Cu(i)-BTA units.
Authors:
Kirsi Salorinne; Xi Chen; Ralf W Troff; Maija Nissinen; Hannu Häkkinen
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-4-25
Journal Detail:
Title:  Nanoscale     Volume:  -     ISSN:  2040-3372     ISO Abbreviation:  -     Publication Date:  2012 Apr 
Date Detail:
Created Date:  2012-4-25     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101525249     Medline TA:  Nanoscale     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Nanoscience Center, Department of Chemistry, University of Jyväskylä, P.O. Box 35, 40014 JYU, Finland. hakkinen.hannu@gmail.com.
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