Document Detail

One-pot solvothermal synthesis of uniform layer-by-layer self-assembled ultrathin hexagonal Gd(2)O(2)S nanoplates and luminescent properties from single doped Eu(3+) and codoped Er(3+), Yb(3)(+).
MedLine Citation:
PMID:  23033159     Owner:  NLM     Status:  Publisher    
Uniform Gd(2)O(2)S flower-like nano-assemblies were prepared through one-pot mild solvothermal synthesis. The parallel nanoplates are the building blocks, ∼3 nm in thickness and 20-30 in diameter. Ethanediamine, the main solvent, plays an important role in dissolving a large amount of sulphur and producing active S(2-) ions, which results in the direct formation of Gd(2)O(2)S. Oleylamine, the capping agent, controls the growth of the plate-like structure. Under UV excitation, the Gd(2)O(2)S:Eu(3+) nano-phosphor shows good red luminescence with a main emission peak at 627 nm. Under 980 nm laser excitation, Gd(2)O(2)S:xYb(3+),1%Er(3+) nano-phosphors exhibit a tuneable emission, shifting from greenish-yellow to orange-yellow, with increasing Yb(3+) content.
Jie Liu; Hongde Luo; Pujun Liu; Lixian Han; Xiao Zheng; Bo Xu; Xibin Yu
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-3
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Department of Chemistry, Shanghai Normal University, Shanghai 200234, People's Republic of China.
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