Document Detail


Oligomerization Oscillations of L-lactic Acid in Solution.
MedLine Citation:
PMID:  22054006     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
We employ high performance liquid chromatography with diode array, evaporative light scattering and mass spectrometric detection to monitor the oligomerization of L-lactic acid in pure acetonitrile and in 70% aqueous ethanol. The production of higher oligomers appears to proceed in an oscillatory fashion. A model is presented that involves the formation of aggregates (micelles), which catalyze the oligomerization.
Authors:
Mieczysław Sajewicz; Milos Dolnik; Dorota Kronenbach; Monika Gontarska; Teresa Kowalska; Irving Robert Epstein
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-11-4
Journal Detail:
Title:  The journal of physical chemistry. A     Volume:  -     ISSN:  1520-5215     ISO Abbreviation:  -     Publication Date:  2011 Nov 
Date Detail:
Created Date:  2011-11-7     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9890903     Medline TA:  J Phys Chem A     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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