Document Detail


Observation of the FeCN and FeCO Vibrations in the Active Site of [NiFe] Hydrogenase by Nuclear Resonance Vibrational Spectroscopy.
MedLine Citation:
PMID:  23136119     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Nuclear inelastic scattering of (57) Fe labeled [NiFe] hydrogenase is shown to give information on different states of the enzyme. It was thus possible to detect and assign FeCO and FeCN bending and stretching vibrations of the active site outside the spectral range of the FeS cluster normal modes.
Authors:
Saeed Kamali; Hongxin Wang; Devrani Mitra; Hideaki Ogata; Wolfgang Lubitz; Brian C Manor; Thomas B Rauchfuss; Deborah Byrne; Violaine Bonnefoy; Francis E Jenney; Michael W W Adams; Yoshitaka Yoda; Ercan Alp; Jiyong Zhao; Stephen P Cramer
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-8
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-8     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Department of Chemistry, University of California, Davis, CA 95616 (USA).
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