Document Detail


Nucleic acid controlled catalysts of carboxylic esters hydrolysis.
MedLine Citation:
PMID:  18851909     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Two Cu(2+)-binding ligands were covalently attached to termini of short DNAs. The optimal compound of this type forms a catalytically inert complex with Cu(2+). In the presence of a complementary nucleic acid the complex is decomposed forming products, which may catalyze hydrolysis of carboxylic acid esters. We have demonstrated that this process can be applied for sequence specific detection of nucleic acids.
Authors:
J??nos Kov??cs; Andriy Mokhir
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2008-09-27
Journal Detail:
Title:  Bioorganic & medicinal chemistry letters     Volume:  18     ISSN:  1464-3405     ISO Abbreviation:  Bioorg. Med. Chem. Lett.     Publication Date:  2008 Nov 
Date Detail:
Created Date:  2009-10-30     Completed Date:  2009-12-29     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9107377     Medline TA:  Bioorg Med Chem Lett     Country:  England    
Other Details:
Languages:  eng     Pagination:  5722-4     Citation Subset:  IM    
Affiliation:
Inorganic Chemistry Institute, University of Heidelberg, In Neuenheimer Feld 270, 69120 Heidelberg, Germany.
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MeSH Terms
Descriptor/Qualifier:
Carboxylic Acids / chemistry*
Catalysis
Chromatography, High Pressure Liquid
Esters
Hydrolysis
Nucleic Acids / chemistry*
Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
Chemical
Reg. No./Substance:
0/Carboxylic Acids; 0/Esters; 0/Nucleic Acids

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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