Document Detail


Novel synthesis of N(4)-substituted 1,4-benzodiazepine-2,5-diones using poly(ethylene glycol) as soluble polymer support.
MedLine Citation:
PMID:  17168679     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
An efficient method for the liquid-phase combinatorial synthesis of N4-substituted 1,4-benzodiazepine-2,5-diones has been developed. Poly(ethylene glycol) (PEG) stepwise reacted with bromoacetyl bromide, a primary amine and 2-azidobenzoic acid to give a potential PEG-bound dipeptide, which was reduced by NaI / acetic acid, along with concurrent cyclization and cleavage of the seven-membered heterocycle from the PEG support.
Authors:
Zhen Rao; Hongdan Peng; Guichun Yang; Zuxing Chen
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Publication Detail:
Type:  Journal Article    
Journal Detail:
Title:  Combinatorial chemistry & high throughput screening     Volume:  9     ISSN:  1386-2073     ISO Abbreviation:  Comb. Chem. High Throughput Screen.     Publication Date:  2006 Dec 
Date Detail:
Created Date:  2006-12-15     Completed Date:  2007-03-07     Revised Date:  2008-11-21    
Medline Journal Info:
Nlm Unique ID:  9810948     Medline TA:  Comb Chem High Throughput Screen     Country:  Netherlands    
Other Details:
Languages:  eng     Pagination:  743-6     Citation Subset:  IM    
Affiliation:
Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University, Faculty of Chemistry and Chemical Engineering, Hubei University, Wuhan, Hubei, PR China.
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MeSH Terms
Descriptor/Qualifier:
Benzodiazepines / chemical synthesis*,  chemistry*
Combinatorial Chemistry Techniques*
Molecular Structure
Nitrogen / chemistry*
Polyethylene Glycols / chemistry*
Solubility
Chemical
Reg. No./Substance:
0/Bz-423; 0/Polyethylene Glycols; 12794-10-4/Benzodiazepines; 7727-37-9/Nitrogen

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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