Document Detail

Novel carboxylated pyrrole- and carbazole-based monomers. Synthesis and electro-oxidation features.
MedLine Citation:
PMID:  17109539     Owner:  NLM     Status:  MEDLINE    
Carboxylated pyrrole (Pyr, a index)- and carbazole (Cbz, b index)-containing monomers 6-7a/b and 9a/b have been readily synthesized from the monobenzyl ester of L-glutamic acid and triamine 2 using Clauson-Kaas and amide coupling reactions. In contrast to Pyr-containing compounds 6-7a, and 9a, the three Cbz-containing monomers 6-7b, and 9b have been found electroactive and were successfully electropolymerized on a Pt electrode resulting in the deposition of corresponding insoluble electroconducting polyCOOH polyCbz-films poly(6-7b) and poly(9b).
Senthil Govindaraji; Philippe Nakache; Vered Marks; Zvika Pomerantz; Arie Zaban; Jean-Paul Lellouche
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  The Journal of organic chemistry     Volume:  71     ISSN:  0022-3263     ISO Abbreviation:  J. Org. Chem.     Publication Date:  2006 Nov 
Date Detail:
Created Date:  2006-11-19     Completed Date:  2007-02-20     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  2985193R     Medline TA:  J Org Chem     Country:  United States    
Other Details:
Languages:  eng     Pagination:  9139-43     Citation Subset:  IM    
Department of Chemistry, Bar-Ilan University, 52900 Ramat-Gan, Israel.
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MeSH Terms
Carbazoles / chemistry*
Magnetic Resonance Spectroscopy
Pyrroles / chemistry*
Spectrometry, Mass, Electrospray Ionization
Spectrometry, Mass, Fast Atom Bombardment
Reg. No./Substance:
0/Carbazoles; 0/Pyrroles

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