| Novel carboxylated pyrrole- and carbazole-based monomers. Synthesis and electro-oxidation features. | |
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MedLine Citation:
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PMID: 17109539 Owner: NLM Status: MEDLINE |
Abstract/OtherAbstract:
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Carboxylated pyrrole (Pyr, a index)- and carbazole (Cbz, b index)-containing monomers 6-7a/b and 9a/b have been readily synthesized from the monobenzyl ester of L-glutamic acid and triamine 2 using Clauson-Kaas and amide coupling reactions. In contrast to Pyr-containing compounds 6-7a, and 9a, the three Cbz-containing monomers 6-7b, and 9b have been found electroactive and were successfully electropolymerized on a Pt electrode resulting in the deposition of corresponding insoluble electroconducting polyCOOH polyCbz-films poly(6-7b) and poly(9b). |
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Authors:
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Senthil Govindaraji; Philippe Nakache; Vered Marks; Zvika Pomerantz; Arie Zaban; Jean-Paul Lellouche |
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Publication Detail:
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Type: Journal Article; Research Support, Non-U.S. Gov't |
Journal Detail:
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Title: The Journal of organic chemistry Volume: 71 ISSN: 0022-3263 ISO Abbreviation: J. Org. Chem. Publication Date: 2006 Nov |
Date Detail:
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Created Date: 2006-11-19 Completed Date: 2007-02-20 Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 2985193R Medline TA: J Org Chem Country: United States |
Other Details:
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Languages: eng Pagination: 9139-43 Citation Subset: IM |
Affiliation:
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Department of Chemistry, Bar-Ilan University, 52900 Ramat-Gan, Israel. |
Export Citation:
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| MeSH Terms | |
Descriptor/Qualifier:
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Carbazoles
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chemistry* Electrochemistry Magnetic Resonance Spectroscopy Oxidation-Reduction Pyrroles / chemistry* Spectrometry, Mass, Electrospray Ionization Spectrometry, Mass, Fast Atom Bombardment |
| Chemical | |
Reg. No./Substance:
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0/Carbazoles; 0/Pyrroles |
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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