Document Detail


A novel tunable green- to yellow-emitting β-YFS:Ce³+ phosphor for solid-state lighting.
MedLine Citation:
PMID:  21732602     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
A Ce(3+)-activated fluorosulfide phosphor (β-YFS:Ce(3+)) was synthesized by solid-state reaction in a sealed tube. The crystal structure has been refined from the XRD profiles and there are two different crystallographic rare earth sites, namely, Y(1) and Y(2), where the Ce(3+) ions occupied. The emission band with a maximum at 495 nm of β-Y(0.99)Ce(0.01)FS phosphor was characterized by the 4f-5d transitions of Ce(3+) ion. With increasing Ce(3+) concentration, the emission variations were observed from 495 to 547 nm. When β-YFS:Ce(3+) phosphors were utilized to incorporate with n-UV/blue chip, greenish-white light with color rendering index of 65-77 were obtained. The results indicate that the tunable green- to yellow-emitting β-YFS:Ce(3+) can serve as a potential phosphor for incorporation in fabrication for solid-state lighting. The preparation, spectroscopic characterization, quantum efficiency, thermal-quenching behavior, and related LED device data are also presented.
Authors:
Yun-Chen Wu; De-Yin Wang; Teng-Ming Chen; Chi-Shen Lee; Kuo-Ju Chen; Hao-Chung Kuo
Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't     Date:  2011-07-18
Journal Detail:
Title:  ACS applied materials & interfaces     Volume:  3     ISSN:  1944-8252     ISO Abbreviation:  ACS Appl Mater Interfaces     Publication Date:  2011 Aug 
Date Detail:
Created Date:  2011-08-24     Completed Date:  2011-12-20     Revised Date:  2012-03-28    
Medline Journal Info:
Nlm Unique ID:  101504991     Medline TA:  ACS Appl Mater Interfaces     Country:  United States    
Other Details:
Languages:  eng     Pagination:  3195-9     Citation Subset:  IM    
Affiliation:
Phosphors Research Laboratory, Department of Applied Chemistry and Institute of Molecular Science, National Chiao Tung University, Hsinchu 30010, Taiwan.
Export Citation:
APA/MLA Format     Download EndNote     Download BibTex
MeSH Terms
Descriptor/Qualifier:
Cerium / chemistry*
Color
Lighting
Quantum Theory
Sulfides / chemistry*
Temperature
Ultraviolet Rays
Chemical
Reg. No./Substance:
0/Sulfides; 7440-45-1/Cerium

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


Previous Document:  Homoleptic Tetranuclear Complexes of Divalent Tin and Lead Tetraolates.
Next Document:  Probabilistic Design of a Near-Surface CO(2) Leak Detection System.