| Non-classical anticancer agents: on the way to water soluble zinc(ii) heteroleptic complexes. | |
MedLine Citation:
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PMID: 23483120 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Two new heteroleptic Zn(ii) complexes of the 4,4'-bis(hydroxymethyl)-2,2'-bipyridine have been synthesized by using different stoichiometric ratios of tropolone. In an attempt to induce the formation of metal complex co-crystals, liquid assisted solid state reaction followed by solvent crystallization has been conducted by using the new Zn(ii) tropolonate derivatives and with saccharin. The novel Zn(ii) species obtained exhibits different structures and properties with respect to their precursors, due to a hydrogen exchange between saccharin and the tropolonate coordinated ligand. |
Authors:
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Barbara Sanz Mendiguchia; Daniela Pucci; Teresa F Mastropietro; Mauro Ghedini; Alessandra Crispini |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2013-3-12 |
Journal Detail:
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Title: Dalton transactions (Cambridge, England : 2003) Volume: - ISSN: 1477-9234 ISO Abbreviation: Dalton Trans Publication Date: 2013 Mar |
Date Detail:
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Created Date: 2013-3-13 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 101176026 Medline TA: Dalton Trans Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Affiliation:
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Centro di Eccellenza CEMIF.CAL, LASCAMM CR-INSTM and Laboratorio Regionale Licryl, CNR-INFM, Dipartimento di Chimica, Università della Calabria, 87030 Arcavacata di Rende (CS), Italy. d.pucci@unical.it. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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