Document Detail

Nitrosyl isomerism in amorphous Mn(TPP)(NO) solids.
MedLine Citation:
PMID:  23143019     Owner:  NLM     Status:  Publisher    
Reaction of NO with amorphous Mn(TPP) layers gives two Mn(TPP)(NO) isomers with linear and bent Mn-N-O geometries that reversibly interconvert with changes in temperature. DFT computations predict that the linear complex is the singlet ground state while the bent structure is a triplet state.
Tigran S Kurtikyan; Vardan A Hayrapetyan; Garik G Martirosyan; Robert K Ghazaryan; Alexei V Iretskii; Hailiang Zhao; Kristine Pierloot; Peter C Ford
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-11-12
Journal Detail:
Title:  Chemical communications (Cambridge, England)     Volume:  -     ISSN:  1364-548X     ISO Abbreviation:  Chem. Commun. (Camb.)     Publication Date:  2012 Nov 
Date Detail:
Created Date:  2012-11-12     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9610838     Medline TA:  Chem Commun (Camb)     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Molecule Structure Research Center (MSRC), National Academy of Sciences, 0014, Yerevan, Armenia.
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