| Nitromethane with IBX/TBAF as a Nitrosating Agent: Synthesis of Nitrosamines from Secondary or Tertiary Amines Under mild Conditions. | |
| | |
MedLine Citation:
|
PMID: 22148366 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
|
Aliphatic or aromatic N,N-disubstituted nitrosamine was generated in fair to excellent yield from the reaction of a secondary or tertiary amine with o-iodoxybenzoic acid (IBX) or o-iodosylbenzoic acid (IBA)/R4NX (X = halide) and nitromethane. The product yield was strongly influenced by both the halide of R4NX and iodanes. IBX gave a higher yield than IBA, while the halides follows F- > Cl- > Br- ~ I-. Nitrous acid formed in-situ from nitromethane and IBX (or IBA)/halides is likely responsible for the observed reaction. |
| | |
Authors:
|
Hima K Potturi; Ras K Gurung; Yuqing Hou |
Related Documents
:
|
10863626 - Fetal macrosomia: etiologic factors. 6049306 - Nutritional requirements of staphylococcus aureus s-6. 22047656 - Production and characterization of biopolyols and polyurethane foams from crude glycero... 7820306 - Influence of fatty acids and bovine serum albumin on the growth of human hepatoma and i... 811656 - Co-oxygenation of organic substrates by the prostaglandin synthetase of sheep vesicular... 15567156 - An enzymatic cycling method for the determination of serum total bile acids with recomb... |
Publication Detail:
|
Type: JOURNAL ARTICLE Date: 2011-12-7 |
Journal Detail:
|
Title: The Journal of organic chemistry Volume: - ISSN: 1520-6904 ISO Abbreviation: - Publication Date: 2011 Dec |
Date Detail:
|
Created Date: 2011-12-13 Completed Date: - Revised Date: - |
Medline Journal Info:
|
Nlm Unique ID: 2985193R Medline TA: J Org Chem Country: - |
Other Details:
|
Languages: ENG Pagination: - Citation Subset: - |
Export Citation:
|
APA/MLA Format Download EndNote Download BibTex |
| MeSH Terms | |
Descriptor/Qualifier:
|
|
From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
Previous Document: Modeling and Development of a Biosensor Based on Optical Relaxation Measurements of Hybrid Nanoparti...
Next Document: A Survey of Mycotoxins in U.S. Distiller's Dried Grains with Solubles from 2009 to 2011.