Document Detail

Nickel-catalyzed C-H direct amination of benzoxazoles with secondary amines.
MedLine Citation:
PMID:  22495579     Owner:  NLM     Status:  In-Data-Review    
In this article, a facile, efficient and practical method for Ni-catalyzed direct C-H amination of benzoxazole with secondary amines has been developed. This procedure requires Ni(OAc)(2)·4H(2)O as catalyst, TBHP as oxidant and acid as the additive. A variety of substituted benzoxazol-2-amines were synthesized in moderate to good yields.
Yaming Li; Jin Liu; Yusheng Xie; Rong Zhang; Kun Jin; Xiuna Wang; Chunying Duan
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Publication Detail:
Type:  Journal Article     Date:  2012-04-03
Journal Detail:
Title:  Organic & biomolecular chemistry     Volume:  10     ISSN:  1477-0539     ISO Abbreviation:  Org. Biomol. Chem.     Publication Date:  2012 May 
Date Detail:
Created Date:  2012-04-12     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101154995     Medline TA:  Org Biomol Chem     Country:  England    
Other Details:
Languages:  eng     Pagination:  3715-20     Citation Subset:  IM    
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, P.R. China.
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