Document Detail

New photoluminescence acylhydrazidate-coordinated complexes.
MedLine Citation:
PMID:  22200047     Owner:  NLM     Status:  Publisher    
Under the hydrothermal conditions, five new acylhydrazidate-containing compounds [Cd(EPDH)(2)(H(2)O)] 1, [Cd(MPDH)(2)] 2, [Zn(MPDH)(2)(H(2)O)(2)]·2H(2)O 3, [Pb(2)(ODPTH)(2)(phen)(2)(H(2)O)(2)] 4 and [Cd(2)(APTH)(4)(phen)(2)]·2H(2)O 5 (EPDH = 5-ethylpyridine-2,3-dicarboxylhydrazidate, MPDH = 6-methylpyridine-2,3-dicarboxylhydrazidate, ODPTH = 4,4'-oxydiphthalhydrazidate, APTH = 3-amiophthalhydrazidate, phen = 1,10-phenanthroline) were luckily obtained. Note that MPDH, EPDH and ODPTH were derived from the hydrothermal in situ acylation reactions between organic polycarboxylic acids and N(2)H(4)·H(2)O, whereas APTH originated from the hydrothermal in situ reduction reaction of NPTH (NPTH = 3-nitrophthalhydrazidate) in the presence of N(2)H(4)·H(2)O. The photoluminescence analysis indicates that all of the title compounds are fluorescent materials with maximum emissions at 530 nm for 1, 540 nm for 2, 517 nm for 3, 413 nm for 4 and 563 nm for 5, respectively. The density functional theory (DFT) calculations on the excited electronic states of compound 3 indicate that the emission is associated with the ligands, corresponding to the charge transfer from the π orbital of the acylhydrazidate ring to the π* orbital of the pyridine ring.
Juan Jin; Fu-Quan Bai; Ming-Jun Jia; Yu Peng; Jie-Hui Yu; Ji-Qing Xu
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-12-23
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  -     Publication Date:  2011 Dec 
Date Detail:
Created Date:  2011-12-26     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Jiefang Road 2519, Changchun, 130023, P.R. China.
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