Document Detail


Necessity of ascorbic acid in the radioligand binding assay for [3H]5-hydroxytryptamine.
MedLine Citation:
PMID:  3774116     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Evidence is presented to suggest that ascorbic acid is required in the radioligand binding assay for [3H]5-hydroxytryptamine ([3H]5-HT, [3H]serotonin). In the absence of ascorbic acid, oxidation of [3H]5-HT occurred if the radioligand solution was left on ice for 1 or 3 hr. The oxidative products were detectable by thin-layer chromatography. They increased the binding significantly, although there was only slight oxidation (less than 1%) of the [3H]5-HT. When ascorbic acid was not used in the radioligand binding assay for [3H]5-HT, even though [3H]5-HT was prepared immediately before incubating with the membranes from the cortex of the rat, the binding also increased. The increased binding of [3H]5-HT had a low affinity (Kd = 14 nM) and high B max (1180 fmol/mg protein), compared to that in the presence of ascorbic acid (Kd = 5 nM; B max = 210 fmol/mg protein). However, the increased binding was not receptor-related because the additional radioactivity was not displaceable by excess of unlabelled 5-HT (10 microM) or d-LSD (d-lysergic acid iethylamide) and anomalous "specific binding" occurred in boiled membranes from cortex, in which the binding sites for 5-HT were destroyed. These results suggest that oxidation of [3H]5-HT may occur during the incubation with membranes and that ascorbic acid is therefore required as an antioxidant.
Authors:
J W Andresen; J C Shih
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Publication Detail:
Type:  Journal Article; Research Support, U.S. Gov't, P.H.S.    
Journal Detail:
Title:  Neuropharmacology     Volume:  25     ISSN:  0028-3908     ISO Abbreviation:  Neuropharmacology     Publication Date:  1986 Aug 
Date Detail:
Created Date:  1986-11-24     Completed Date:  1986-11-24     Revised Date:  2007-11-14    
Medline Journal Info:
Nlm Unique ID:  0236217     Medline TA:  Neuropharmacology     Country:  ENGLAND    
Other Details:
Languages:  eng     Pagination:  869-75     Citation Subset:  IM    
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MeSH Terms
Descriptor/Qualifier:
Animals
Ascorbic Acid / pharmacology*
Cerebral Cortex / analysis*,  metabolism
Male
Oxidation-Reduction
Radioligand Assay
Rats
Rats, Inbred Strains
Receptors, Serotonin / analysis*,  metabolism
Serotonin / metabolism*
Grant Support
ID/Acronym/Agency:
MH37020/MH/NIMH NIH HHS; MH39085/MH/NIMH NIH HHS; S07 RR05792/RR/NCRR NIH HHS
Chemical
Reg. No./Substance:
0/Receptors, Serotonin; 50-67-9/Serotonin; 50-81-7/Ascorbic Acid

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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