Document Detail


Nanostructured Protein Repellant Amphiphilic Copolymer Coatings with Optimized Surface Energy by Inductively Excited Low Pressure Plasma.
MedLine Citation:
PMID:  22029599     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Statistically designed amphiphilic copolymer coatings were deposited on to Thermanox®, Si wafer and quartz crystal microbalance (QCM) substrates via Plasma Enhanced Chemical Vapor Deposition (PECVD) of 1H,1H,2H,2H-perfluorodecyl acrylate (PFDA) and diethylene glycol vinyl ether (DEGVE) in a Inductively Excited Low Pressure Plasma reactor. Plasma deposited amphiphilic coatings were characterized by Field Emission Scanning Electron Microscopy (FESEM), X-ray Photoelectron Spectroscopy (XPS), Atomic Force Microscopy (AFM) and Water Contact Angle (WCA) techniques. The surface energy of the coatings can be adjusted between 12 to 70 mJ/m2. The roughness of the coatings can be tailored de-pending on the plasma mode used. A very smooth coatings was deposited with a CW (continuous wave) power, whereas, a rougher surface with Ra in the range of 2 to 12 nm were deposited with the PW (pulsed wave) mode. The nanometer scale roughness of amphiphilic PFDA-co-DEGVE coatings was found to be in the range of the size of the two proteins namely BSA & Lysozyme used to examine for the antifouling properties of the surfaces. The results show that the statistically designed surfaces, presenting a surface energy around 25 mJ/m2, present no adhesion with respect to both proteins measured by QCM.
Authors:
Sudhir Bhatt; Jérôme Pulpytel; Giacomo Ceccone; Patrícia Lisboa; Francois Rossi; Virendra Kumar; Farzaneh Arefi-Khonsari
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2011-10-26
Journal Detail:
Title:  Langmuir : the ACS journal of surfaces and colloids     Volume:  -     ISSN:  1520-5827     ISO Abbreviation:  -     Publication Date:  2011 Oct 
Date Detail:
Created Date:  2011-10-27     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9882736     Medline TA:  Langmuir     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
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