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Nano Grape Formation by isotactic-Poly(methacrylic acid)-block-Poly(butyl acrylate).
MedLine Citation:
PMID:  21590960     Owner:  NLM     Status:  In-Data-Review    
Abstract/OtherAbstract:
A novel approach is employed to produce core-corona nanospheres, which introduces a stereoregular hydrophilic part to an amphiphilic block copolymer. The resultant morphology is reported using isotactic-poly(methacrylic acid)-block-poly(butyl acrylate). Infrared spectroscopy revealed a supramolecular interaction, and X ray diffraction revealed the crystallization of the outer isotactic-poly(methacrylic acid) part. The nanostructure, which looks like a nanosized 'grape', was formed when nanospheres and nanofibers coexisted simultaneously and partially fused.
Authors:
Hiroharu Ajiro; Mitsuru Akashi
Publication Detail:
Type:  Journal Article     Date:  2010-02-09
Journal Detail:
Title:  Macromolecular rapid communications     Volume:  31     ISSN:  1521-3927     ISO Abbreviation:  Macromol Rapid Commun     Publication Date:  2010 Apr 
Date Detail:
Created Date:  2011-05-18     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  9888239     Medline TA:  Macromol Rapid Commun     Country:  Germany    
Other Details:
Languages:  eng     Pagination:  714-7     Citation Subset:  -    
Copyright Information:
Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
Department of Applied Chemistry, Graduate School of Engineering, and The Center for Advanced Medical Engineering and Informatics, Osaka University, Suita, Osaka 565-0871, Japan.
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