| [(NHC)Yb{N(SiMe(3) )(2) }(2) ]-Catalyzed Cross-Dehydrogenative Coupling of Silanes with Amines. | |
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MedLine Citation:
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PMID: 23038165 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Top cat: [(NHC)Yb{N(SiMe(3) )(2) }(2) ] adducts (NHC=N-heterocyclic carbene) are efficient catalysts for catalytic cross-dehydrogenative coupling of silanes with a range of primary and secondary amines to yield silylamines in high yields (82-100 %) under mild reaction conditions. The catalytic activity and selectivity of the rare-earth-metal silylamides are modulated by altering the steric bulk of the NHC. |
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Authors:
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Weilong Xie; Hongfan Hu; Chunming Cui |
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Publication Detail:
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Type: JOURNAL ARTICLE Date: 2012-10-4 |
Journal Detail:
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Title: Angewandte Chemie (International ed. in English) Volume: - ISSN: 1521-3773 ISO Abbreviation: Angew. Chem. Int. Ed. Engl. Publication Date: 2012 Oct |
Date Detail:
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Created Date: 2012-10-5 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0370543 Medline TA: Angew Chem Int Ed Engl Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071 (China) skleoc.nankai.edu.cn. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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