Document Detail


[(NHC)Yb{N(SiMe(3) )(2) }(2) ]-Catalyzed Cross-Dehydrogenative Coupling of Silanes with Amines.
MedLine Citation:
PMID:  23038165     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Top cat: [(NHC)Yb{N(SiMe(3) )(2) }(2) ] adducts (NHC=N-heterocyclic carbene) are efficient catalysts for catalytic cross-dehydrogenative coupling of silanes with a range of primary and secondary amines to yield silylamines in high yields (82-100 %) under mild reaction conditions. The catalytic activity and selectivity of the rare-earth-metal silylamides are modulated by altering the steric bulk of the NHC.
Authors:
Weilong Xie; Hongfan Hu; Chunming Cui
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-4
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  Angew. Chem. Int. Ed. Engl.     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-5     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Affiliation:
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071 (China) skleoc.nankai.edu.cn.
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