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N-Heterocyclic Carbene Dichotomy in Pd-Catalyzed Acylation of Aryl Chlorides via C-H Bond Functionalization.
MedLine Citation:
PMID:  23030460     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The first Pd-catalyzed intramolecular acylation of aryl chlorides via C-H bond functionalization is presented. The method allows for the synthesis of a variety of elusive benzocyclobutenones with a wide range of functional groups and substitution patterns. We demonstrate that a change in the ligand backbone dictates the selectivity pattern.
Authors:
Areli Flores-Gaspar; Alvaro Gutiérrez-Bonet; Ruben Martin
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-10-3
Journal Detail:
Title:  Organic letters     Volume:  -     ISSN:  1523-7052     ISO Abbreviation:  Org. Lett.     Publication Date:  2012 Oct 
Date Detail:
Created Date:  2012-10-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  100890393     Medline TA:  Org Lett     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Institute of Chemical Research of Catalonia (ICIQ) , Av. Països Catalans, 16, 43007, Tarragona, Spain.
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