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Molecular systems for light driven hydrogen production.
MedLine Citation:
PMID:  23014879     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Recent work towards the production of hydrogen via reduction of protons is described. Most of the systems examined in this perspective use a molecular chromophore for harvesting visible light, a catalyst, which is reduced by the excited (or reduced) chromophore, and finally a sacrificial electron source to oxidatively or reductively quench the chromophore. The reduced catalyst is then responsible for the reduction of protons resulting in hydrogen evolution. Relevant mechanistic work on this topic is also discussed.
Authors:
William T Eckenhoff; Richard Eisenberg
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-9-27
Journal Detail:
Title:  Dalton transactions (Cambridge, England : 2003)     Volume:  -     ISSN:  1477-9234     ISO Abbreviation:  Dalton Trans     Publication Date:  2012 Sep 
Date Detail:
Created Date:  2012-9-27     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101176026     Medline TA:  Dalton Trans     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
Department of Chemistry, University of Rochester, Rochester, New York 14627, USA. eisenberg@chem.rochester.edu.
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