Document Detail

Molecular Oxygen as a Redox Catalyst in Intramolecular Photocycloadditions of Coumarins.
MedLine Citation:
PMID:  22555980     Owner:  NLM     Status:  Publisher    
Oxygen as a catalyst! While oxygen is usually excluded in nonoxidative photochemical reactions, the photocycloaddition of 3-(alk-4-en-1-yl)-substituted coumarins greatly benefits from the presence of O(2) , which was shown to act as a redox catalyst, preferentially in combination with the common antioxidant 3,5-di-tert-butyl-4-hydroxytoluene (BHT).
Darius Paul Kranz; Axel Georg Griesbeck; Ronald Alle; Raul Perez-Ruiz; Jörg Martin Neudörfl; Klaus Meerholz; Hans-Günther Schmalz
Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-5-3
Journal Detail:
Title:  Angewandte Chemie (International ed. in English)     Volume:  -     ISSN:  1521-3773     ISO Abbreviation:  -     Publication Date:  2012 May 
Date Detail:
Created Date:  2012-5-4     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0370543     Medline TA:  Angew Chem Int Ed Engl     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Department für Chemie, Universität zu Köln, Greinstrasse 4, 50939 Köln (Germany).
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