| Modulating the Acidity-Highly Acidic Brønsted Acids in Asymmetric Catalysis. | |
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MedLine Citation:
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PMID: 21678531 Owner: NLM Status: Publisher |
Abstract/OtherAbstract:
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Recently, chiral highly acidic Brønsted acids have emerged as powerful catalysts for enantioselective CC and CX bond-forming reactions. Their strong acidity renders them valuable tools for the activation of imines, carbonyl compounds, and other weakly basic substrates. As a result, new perspectives are opened and highly stereoselective transformations based on the concept of chiral contact-ion-pair catalysis can be realized. This Minireview gives an overview of the design and application of these new organocatalysts and presents recent results in this rapidly growing field. |
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Authors:
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Magnus Rueping; Boris J Nachtsheim; Winai Ieawsuwan; Iuliana Atodiresei |
Publication Detail:
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Type: JOURNAL ARTICLE Date: 2011-6-15 |
Journal Detail:
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Title: Angewandte Chemie (International ed. in English) Volume: - ISSN: 1521-3773 ISO Abbreviation: - Publication Date: 2011 Jun |
Date Detail:
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Created Date: 2011-6-16 Completed Date: - Revised Date: - |
Medline Journal Info:
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Nlm Unique ID: 0370543 Medline TA: Angew Chem Int Ed Engl Country: - |
Other Details:
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Languages: ENG Pagination: - Citation Subset: - |
Copyright Information:
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Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Affiliation:
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Institut für Organische Chemie, RWTH Aachen, Landoltweg 1, 52074 Aachen (Germany), Fax: (+94) 241-80-92665. magnus.rueping@rwth-aachen.de. |
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From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine
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