Document Detail


Modeling adsorption rate of organic micropollutants present in landfill leachates onto granular activated carbon.
MedLine Citation:
PMID:  22858399     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
The overall adsorption rate of single micropollutants present in landfill leachates such as phthalic acid (PA), bisphenol A (BPA), diphenolic acid (DPA), 2,4-dichlorophenoxy-acetic acid (2,4-D), and 4-chloro-2-methylphenoxyacetic acid (MCPA) on two commercial activated carbons was studied. The experimental data obtained were interpreted by using a diffusional model (PVSDM) that considers external mass transport, intraparticle diffusion, and adsorption on an active site. Furthermore, the concentration decay data were interpreted by using kinetics models. Results revealed that PVSDM model satisfactorily fitted the experimental data of adsorption rate on activated carbon. The tortuosity factor of the activated carbons used ranged from 2 to 4. The contribution of pore volume diffusion represented more than 92% of intraparticle diffusion confirming that pore volume diffusion is the controlling mechanism of the overall rate of adsorption and surface diffusion can be neglected. The experimental data were satisfactorily fitted the kinetic models. The second-order kinetic model was better fitted the experimental adsorption data than the first-order model.
Authors:
Raúl Ocampo-Pérez; Mahmoud M Abdel Daiem; José Rivera-Utrilla; José D Méndez-Díaz; Manuel Sánchez-Polo
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2012-7-16
Journal Detail:
Title:  Journal of colloid and interface science     Volume:  -     ISSN:  1095-7103     ISO Abbreviation:  J Colloid Interface Sci     Publication Date:  2012 Jul 
Date Detail:
Created Date:  2012-8-3     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  0043125     Medline TA:  J Colloid Interface Sci     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Copyright Information:
Copyright © 2012 Elsevier Inc. All rights reserved.
Affiliation:
Inorganic Chemistry Department, Faculty of Science, University of Granada, 18071 Granada, Spain.
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