Document Detail


Migration of methylethynyl group in a long-lived carbocation.
MedLine Citation:
PMID:  23338527     Owner:  NLM     Status:  Publisher    
Abstract/OtherAbstract:
Degenerate 1,2-shift of methylethynyl group in long-lived 9,10-dimethyl-9-methylethynyl-phenanthrenium ion has been detected by NMR. This is the first example of ethynyl migration in a long-lived carbocation.
Authors:
George E Salnikov; Alexander M Genaev; Vladimir A Bushmelev; Vyacheslav G Shubin
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Publication Detail:
Type:  JOURNAL ARTICLE     Date:  2013-1-22
Journal Detail:
Title:  Organic & biomolecular chemistry     Volume:  -     ISSN:  1477-0539     ISO Abbreviation:  Org. Biomol. Chem.     Publication Date:  2013 Jan 
Date Detail:
Created Date:  2013-1-22     Completed Date:  -     Revised Date:  -    
Medline Journal Info:
Nlm Unique ID:  101154995     Medline TA:  Org Biomol Chem     Country:  -    
Other Details:
Languages:  ENG     Pagination:  -     Citation Subset:  -    
Affiliation:
N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Academician Lavrent'ev Ave., 9, Novosibirsk 630090, Russian Federation. genaev@nioch.nsc.ru.
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