Document Detail


Migration of 4-nonylphenol from polyvinyl chloride food packaging films into food simulants and foods.
MedLine Citation:
PMID:  11288913     Owner:  NLM     Status:  MEDLINE    
Abstract/OtherAbstract:
Migration of 4-nonylphenol (NP) from polyvinyl chloride (PVC) films for food packaging into food simulants and foods has been studied in domestic applications such as wrapping of food and reheating in a microwave oven. The migration of NP from the PVC films was determined by high-performance liquid chromatography with electrochemical coulometric-array detection (LC/ED). Twelve PVC films intended for commercial use and ten for domestic applications (total: 22 samples) were analysed. Some of the PVC films (two home-use and ten retail-use) contained NP at concentrations of between 500 and 3300 microg/g. Migration of NP from the films was influenced by the test conditions (n-heptane at 25 degrees C for 60 min, distilled water at 60 degrees C for 30 min and 4% acetic acid at 60 degrees C for 30 min). The amount of NP migrating from the PVC films into n-heptane (0.33-1.6 microg/cm2) was higher than the amount migrating into distilled water or 4% acetic acid (up to 9.7 ng/cm2) for the 11 films in which NP was detected. Up to 0.23% of the NP migrated into distilled water and 4% acetic acid and up to 62.5% into n-heptane. In addition, we investigated NP migration into cooked rice samples wrapped in PVC film. Using spiked samples the method gave an average recovery of 83.7% (n = 5) with a standard deviation of 2.5%. Migration of NP ranged from not detectable (< 1.0 ng/g) to 410.0 ng/g by reheating samples in a microwave oven for 1 min and from not detectable to 76.5 ng/g by keeping samples at room temperature for 30 min.
Authors:
K Inoue; S Kondo; Y Yoshie; K Kato; Y Yoshimura; M Horie; H Nakazawa
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Publication Detail:
Type:  Journal Article; Research Support, Non-U.S. Gov't    
Journal Detail:
Title:  Food additives and contaminants     Volume:  18     ISSN:  0265-203X     ISO Abbreviation:  Food Addit Contam     Publication Date:  2001 Feb 
Date Detail:
Created Date:  2001-04-05     Completed Date:  2001-04-19     Revised Date:  2006-11-15    
Medline Journal Info:
Nlm Unique ID:  8500474     Medline TA:  Food Addit Contam     Country:  England    
Other Details:
Languages:  eng     Pagination:  157-64     Citation Subset:  IM    
Affiliation:
Department of Analytical Chemistry, Faculty of Pharmaceutical Sciences, Hoshi University,Tokyo, Japan.
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MeSH Terms
Descriptor/Qualifier:
Chromatography, High Pressure Liquid / methods
Electrochemistry / methods
Food Contamination*
Food Packaging*
Humans
Oryza sativa / chemistry
Phenols / chemistry*
Polyvinyl Chloride / chemistry*
Chemical
Reg. No./Substance:
0/Phenols; 104-40-5/4-nonylphenol; 9002-86-2/Polyvinyl Chloride

From MEDLINE®/PubMed®, a database of the U.S. National Library of Medicine


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